i-carbanide, i-chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

I-Palladium(II) Chloro complex [(C8H12)(Cl)Pd] yenziwa ngokudityaniswa phakathi kwe-PdCl4 kunye neemolekyuli ze-trans-(1R,5S)-cycloocta-1,5-diene ngokusebenzisa iibhondi ze-dative. Imveliso ephumayo iqulethe i-dienyl ligand enye ebotshelelwe kwiziko ngalinye lesinyithi ezine ngokusebenzisa i-eta-coordination. Le complex inozinzo oluphezulu lobushushu ngenxa yamandla aqinileyo e-intermolecular ngaphakathi kwesakhiwo. Ukusetyenziswa kwayo kuxhomekeke kakhulu kwiinkqubo ze-catalytic ezibandakanya i-cross coupling reaction. Umzekelo, olu hlobo lwenza kube lula ukwakheka kwe-C-C bond ngexesha le-Suzuki Coupling Reaction equka ukudibanisa ii-athomu ze-carbon ezixutyiweyo ze-sp2 kunye kusetyenziswa ii-boronic acids njengee-nucleophiles. Ibhondi entsha ephumayo iphucula iipropati zezinto ezisetyenziswa kwizixhobo ze-elektroniki ngaloo ndlela zizenza zisebenze ngakumbi. Ngaphezu koko, le catalyst ifumana ukusetyenziswa kwi-Sonogashira coupling reaction apho ii-athomu ze-sp hybridized zidityaniswe kunye kusetyenziswa ii-alkynes zesiphelo ezikhokelela ekwakhiweni kwebhondi ye-C-C ngaloo ndlela kwakhiwa amaqela amatsha asebenzayo anezicelo ezinokubakho kwiindawo ezahlukeneyo kubandakanya ukwenziwa kwamayeza kunye nesayensi yezinto.