I-Rhodium, i-di-m-chlorobis[(1,2,5,6-h)-1,5-hexadiene]di- CAS:32965-49-4

I-C12H20Cl2Rh2Rhodium, i-di-m-chlorobis[(1,2,5,6-h)-1,5-hexadiene] idlala indima ebalulekileyo kwiindawo ezahlukeneyo ezifana nekhemistri, isayensi yezinto ezibonakalayo, njl.njl., ngenxa yeempawu zayo ezikhethekileyo. Ngokukodwa, isicelo esinye esikhulu sikwiCatalysis - isebenza njengesikhuthazi esiguquguqukayo kwiintlobo ezininzi zotshintsho kubandakanya i-alkene metathesis, i-hydrosilylation, i-alkyne trimerization phakathi kwezinye. Olu buchule luvela kulwakhiwo lwayo oluthile lwejometri oluququzelela ukudibana phakathi kwe-square planar (SP) kunye ne-trigonal prismatic (TP) geometries kuxhomekeke kwimo yokubopha ye-substrate. Ngaphezu koko, ngenxa yesakhiwo sayo esizinzileyo xa sithelekiswa ne-metal carbonyl precursors zemveli, i-RhCl(CO)(PPh3)3, i-Rhodium, i-di-m-chlorobis[(1,2,5,6-h)-1,5-hexadiene], inokumelana okuphezulu nokubola ngexesha lokugcina nokuthuthwa. Ngenxa yoko, iya ithandwa ngakumbi kwiinkqubo zemveliso yemizi-mveliso ezibandakanya i-metal carbonyl precursors. Ngamafutshane, ngenxa yezi mpawu, iRhodium, di-m-chlorobis[(1,2,5,6-h)-1,5-hexadiene], inoluhlu olubanzi lokusetyenziswa oluqala kwiinjongo zophando ukuya kwizicelo zoshishino. Amandla ayo okusebenza njengomanduleli osebenzayo ayenza ibe luncedo kakhulu kwicandelo lee-metal carbonyl complexes.